Articles from CALCE News© Spring/Summer 2003 issue


CALCE R&D Model Influential Around the World

Since its beginnings in the 1980s, the CALCE Electronic Products and Systems Center (EPSC) has enjoyed unparalleled growth and has built an international reputation as a leader in electronic systems design and analysis. Today, the CALCE EPSC is a driving force behind the development and implementation of physics-of-failure approaches to reliability, as well as a world leader in accelerated testing, failure analysis, and electronic parts selection and management.

The center currently works with over 100 international organizations providing research support and information services. CALCE EPSC collaborates on failure and reliability analysis with City University of Hong Kong; on virtual qualification analysis and software development with Hong Kong University of Science and Technology and with Fudan University in Shanghai; on thermal management with ITRI in Taiwan; and on the reliability of lead-free solders with Tatung in Taiwan and RIST in Korea. In the past six months, 13 new organizations have joined the CALCE Consortium, 5 of them from outside the U.S.A.

The CALCE EPSC represents a desirable model for research centers in the way it incorporates industry and collaborative research. Recently, the Secretary of the Ministry of Commerce, Industry and Energy of Korea announced plans to build a professional research center for excellence modeled after the CALCE EPSC. The center will be located at the Han Yang University and its mission will be focused on improving the reliability of Korean mechanical and electronic components, and developing value-added products. Plans are also under way for establishing a TWI/CALCE Electronics and Systems Reliability Center based in the United Kingdom. This center will act as a central hub for reliability issues in the UK and the rest of Europe.

CALCE EPSC faculty currently serve as editors for 6 internationally prestigious journals. They are also serving as authors, keynote speakers and chairs of international conferences. These contacts identify technology issues early and keep research efforts focused on leading industry needs.

Recently, Prof. Y.C. Chan, EPA Center of City University of Hong Kong and CALCE EPSC co-hosted the International IEEE Conference on the Business of Electronic Product Reliability and Liability in Hong Kong. In June of this year, they will cooperate on another conference on Asian Green Electronics Manufacturing that will be held in Shenzhen, China. For more information on the Center’s expertise and resources, contact Prof. Michael Pecht at 301-405-5323.
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Intellectual Property and Lead-Free Solders

Lead-free patents began to be issued in significant numbers in the US by the late 1980s, mostly as plumbing alloys. However, the lead-free movement in the electronics industry has the potential to add significant value to intellectual property in this domain. This justifies the exponential increase in the number of lead-free patents filed and issued, as observed by CALCE EPSC researchers.

North American, Japanese and European legislation regarding lead in electronic devices is vastly different. The US simply requires that the release of lead or lead compounds be reported. In Japan, household electronics must be recycled, but lead is largely being eliminated voluntarily. Japanese manufacturers see an advantage in lead-free technology for consumer preference. Europe has imposed a ban on lead in electronics, effective in 2006, but European companies do not publicize the progress of their lead-free programs as do the Japanese. In fact, the Japanese zeal for lead-free products has carried over into the domain of patents, where Japanese acquisitions of lead-free intellectual property far exceed those of any other country

It appears from the work already performed that the future of the National Electronics Manufacturing Initiative (NEMI) recommended alloy may not be as bright as was originally thought. The patent situation has changed since the NEMI- recommended composition was decided, and continues to change rapidly. At present, a few patents in the US and in Japan have been identified as potential obstacles to the widespread use of Sn-Ag-Cu solders resembling the NEMI alloy. Yet what may be more unsettling is if a number of Sn-Ag-Cu patent applications currently pending in the US and in Europe are granted. There is one US patent pending that lays claim to a composition that is practically identical to the NEMI alloy. Moreover, several Japanese patent applications in Europe are so close to the NEMI composition that overlap may arise in processing.

The lack of an apparent “baseline?against which all compositions can be easily compared results in potential overlap between compositions. Claim breadth can also be a problem, given that many patents cover not only a wide range of compositions, but also how the compositions are made or used. For example, lead-free patents have been found wherein applications of a solder as a joint or interface between components, a PCB or electronic component joined with the solder, and a joint made with the specified solder by every known technique were included within the scope of a single patent.

In order to deal with increasing lead-free solder patents, claims per patent and complexity of claims, CALCE EPSC is developing a lead-free IP software tool that includes a lead-free patent database. The database already contains the claims of over three hundred lead-free patents worldwide. The software will identify if a given solder formulation is covered under an existing patent.

For a short course at your organization on lead-free IP issues or on lead-free issues in general, contact Prof. Michael Pechtor Dr. Diganta Das.
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Health and Life Consumption Monitoring

For the past four years, the CALCE EPSC has been conducting research on health and life consumption monitoring of electronic systems based on a physics-of-failure (PoF) approach.

Life consumption monitoring (LCM) is a method to assess a product’s reliability based on its remaining life in a given life-cycle environment. The process involves continuous or periodic measurement, sensing, recording, and interpretation of physical parameters associated with a product’s degradation. By determining the product’s health based on actual life-cycle application conditions, procedures can be developed to assess and maintain the product.

CALCE has demonstrated the life consumption methodology in an automotive underhood environment through three case studies. FMEA was used to recognize potential failure modes, determine the root causes of the failure modes and then determine the relevant environmental parameters. A data logger was used, along with environmental sensors, to continuously monitor and record environmental loads on a circuit card assembly. The recorded data was simplified and used with calcePWA reliability analysis software to estimate the remaining life. CALCE was able to characterize the impact of shock profiles resulting from a car accident on the circuit card assembly. The performance of the circuit card assembly was checked in real time through resistance monitoring. The remaining life of the circuit card assembly was predicted at different stages of the experiment with the available amount of information. The most accurate prediction was obtained through the life consumption monitoring approach, taking into account the shock caused by the accident.

Estimating the impact of sudden changes in life cycle environment in real time can have many advantages in making a risk-informed maintenance decision. For example, the estimated remaining life after an accident can be compared with the next mission requirement to ensure that there is enough life left. If required, the mission requirement of the product can be made less severe to get the intended life. This concept is known as “extension of life.?

In-situ Semiconductor Health Monitors: Recently CALCE has been working on applications of in-situ semiconductor health monitors for health and life consumption monitoring. In-situ health monitors are pre-calibrated cells (circuits) that are co-located with the actual circuit on a semiconductor device. The in-situ health monitors thus experience the same manufacturing process and environmental parameters as the actual circuit. Selected failure mechanisms are accelerated in the health monitors by changing the operational parameters. This can be achieved by increasing the current density inside them. Because of accelerated failure mechanisms, in-situ health monitors have higher failure rates than actual circuits over the entire product life. The failure distribution of the in-situ health monitors is statistically calibrated at a point before the onset of the circuit failure distribution, thereby predicting failure. The acceleration factors of the health monitors can also be calibrated.

For more information on health and life consumption monitoring initiatives at the CALCE EPSC, contact Prof. Michael Pecht.
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Effect of Mold Compound Swelling on PEM Reliability

Plastic encapsulated microcircuits (PEMs) still dominate the market share of microcircuit sales worldwide due to their advantages in size, weight, performance and cost. Despite these advantages, one important disadvantage is that polymeric mold compounds absorb moisture, and thus swell, when exposed to a humid environment. Hygroscopic stresses arise in a PEM when the mold compound swells upon absorbing moisture and the lead frame, die paddle and silicon die do not experience swelling. Similar to the thermal stress produced by the mismatch in coefficient of thermal expansion (CTE) between adjacent materials, the hygroscopic stress increases as the hygroscopic swelling coefficient of the mold compound increases. Accurate measurement of hygroscopic swelling is essential in assessing the effect of hygroscopic stresses on package reliability. However, only limited data on hygroscopic swelling can be found in the literature and the results are somewhat inconsistent due to the difficulty associated with ascertaining hygroscopic swelling values.

In a recent study (C02-20), CALCE developed a novel procedure to measure the coefficient of hygroscopic contraction (CHC) of mold compounds. The procedure employs a whole-field in-plane displacement measurement technique with submicron sensitivity and has numerous advantages over the existing methods, which are essentially point-measurement methods. The new procedure allows simultaneous measurement of hygroscopic swelling in both in-plane directions (x and y), while effectively canceling thermally induced deformations. A large gage length nullifies the point-to-point variation within the sample and the high sensitivity provides high measurement accuracy.

The procedure was used to analyze three commercially available mold compounds (labeled A, B and C). Typical results are shown in Figure 1, where hygroscopic strains obtained from three specimens of mold compound sample “A?are plotted against moisture content (%). The fringe patterns represent the deformations of a reference sample at a time zero and a test coupon at four hundred hours of desorption after the virtual saturation condition was achieved. It is evident that a linear relationship exists between swelling and moisture content. The constant of linearity is called the coefficient of hygroscopic contraction (CHC). The CHC is a material property of the mold compound and, if it is known, the hygroscopic strain can be determined by measuring the moisture content in the mold compound, analogous to the thermally-induced strain, which can be determined if a CTE and DT are known.

The CHC at 85ºC for the three mold compounds was 0.26, 0.22 and 0.22 (%eh/%C). The corresponding maximum moisture content in each mold compounds A, B and C at the virtual equilibrium at 85ºC/85%RH was 0.50%, 0.54% and 0.34%, respectively. The leadframe absorbs no moisture and does not undergo any hygroscopic strain. Therefore, the resulting hygroscopic mismatch strains between the mold compound and a copper leadframe should be identical to the swelling strain of the mold compound. The hygroscopic swelling strains were determined by multiplying the CHC by the moisture maximum content; they were 0.13%, 0.12% and 0.07% for mold compounds A, B and C, respectively.

The coefficient of thermal expansion of mold compounds A, B and C below their glass transition temperature are 13, 17 and 11 ppm/°C, respectively. The CTE of the copper leadframe is 17 ppm/°C. If a change in temperature of 100ºC is considered, the thermal mismatch strains at the mold compound/copper interface are 0.04%, 0% and 0.06%. Therefore, the hygroscopic mismatch strains at 85ºC/85%RH of samples “A?and “B?are over three times greater than the thermal mismatch strains. Mold compound sample “C?shows hygroscopic and thermal mismatch strains of the same magnitude.

The above results imply that hygroscopic swelling effects may have a significant impact on PEM reliability. According to the SAE document, Recommended Environmental Practices for Electronic Equipment Design, electronic equipment is commonly subjected to a 38ºC/95%RH environment throughout the automobile and environments of 66ºC/80%RH in multiple locations in the automobile. In such environments, where packages are subjected to both a temperature excursion and relative humidity change, hygroscopic strains must be considered for reliability assessment.

Accelerated life testing conditions such as a HAST (Highly Accelerated Stress Test) chamber, in which temperature, humidity and pressure are used, may also present complications due to hygroscopic swelling issues. The temperature range in a HAST chamber is typically from 100ºC to 150ºC, the relative humidity is typically over 70 percent, and the pressure can be up to 50 psi. These conditions will drastically increase the amount of moisture absorbed by the polymeric materials in a package, and therefore greatly increase hygroscopic swelling. The experimental results presented here imply that hygroscopic swelling would play an important role in the cycles-to-failure of the package being tested. For more information, contact Dr. Bongtae Han.


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Power Electronics Reliability Efforts at the CALCE EPSC

Many next generation electronic products will rely on programmable solid-state modules for controlling and distributing power. These products will include not only major defense systems such as the electric tank and the next generation submarine, but also commercial products such as motor drives, electric vehicles, robotics, and telecommunications. The use of solid-state modules for power conversion and distribution has the potential to significantly improve the efficiency and performance of these electronic products. However, as power supplies are often the heaviest and largest volume components of electronic products, there is a need to develop more compact, modular, lower cost power packaging structures that can ensure reliable operation of the module under harsh environmental (high temperatures and humidity, salt spray) and operational (high voltages, currents and power dissipation levels) loading conditions. Module reliability is essential to maximize performance, minimize life cycle cost, and ensure safety.

Cost effective development, manufacture and use of power modules will, therefore, require a fast and an inexpensive method of evaluating reliability in the earliest stages of conceptual design. To promote this development, CALCE EPSC, with the sponsorship of the Office of Naval Research and Consortium members, has developed a set of new physics-of-failure models to address the dominant failure mechanisms in power electronic modules. Failure mechanisms addressed include:

  • fatigue of aluminum wedge wirebonds
  • fatigue of high lead and lead-free solder die attach
  • fracture of DBC (direct bonded copper) alumina substrates
  • fatigue and stress relaxation of spring-loaded pressure contacts

Each model consists of a stress and damage model that uses the environmental and operational loads, the system architecture and the system materials as the inputs. The stress model describes the system’s stress response to the applied loads; the damage model describes the material response to the stress in terms of number of cycles or number of hours to failure.

These models have been validated against accelerated thermal cycling test results on sample coupons consisting of aluminum wires bonded to DBC substrates, and against thermal shock test results on actual ceramic hybrid power modules. The models are being used to perform design reliability assessments on DC/DC converters this year as part of CALCE core research project C03-11. In addition, the models have been used to perform virtual qualification and/or design assessments of ceramic hybrid power electronic modules for a number of power electronics manufacturers and OEMs this year.

If you are interested in learning more about these efforts or in having power electronic modules assessed for reliability, please contact Dr. Patrick McCluskey at 301-405-0279.
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Electrochemical Migration on Printed Wiring Boards

Electrochemical migration (ECM) is defined by the Institute for Interconnecting and Packaging Electronic Circuits (IPC) as the growth of conductive metal filaments on a printed circuit board (PCB) through an electrolytic solution under the influence of a DC voltage bias [IPC-TR-467A, 1997]. ECM can occur between leads and interconnects, connector pins, electrodes in a capacitor, and traces on a PCB. ECM is considered primarily a surface phenomenon to differentiate it from conductive filament formation (CFF), which occurs internally in the circuit board.

ECM can cause shorts due to the growth of metallic dendrites and is often difficult to identify because the fragile dendrite structure will burn, often leaving little trace it was there. These failures are often intermittent and tend to be the primary cause of failure in electronics that operate in benign environments, such as telecommunications. As component pitch reduces and the use of leadless packages increase, the amount of contamination trapped under packages may increase unless new cleaning methodologies are used; hence, the occurrence of ECM can be expected to rise.

An electrolytic solution, contamination, and a voltage bias are necessary for ECM to occur, although some metals (e.g., silver) may migrate with no contamination present. The solution is usually from relative humidity that provides a water source. Water can then absorb to the surface. Any contamination on the surface, such as halides or weak organic acids, can increase the conductivity of the water. Once this solution bridges two oppositely biased conductors a local electrochemical cell is created. Metal atoms are dissolved into solution at the anode, creating a metal ion. The metal ion then moves through the solution and is deposited at the cathode. This process continues, forming metal dendrites.

The primary factors affecting ECM are voltage bias, relative humidity, temperature, contamination type and amount, conductor metallization, and conductor spacing. As voltage bias, relative humidity, temperature, and contamination concentrations increase and conductor spacing decreases, ECM may become more prevalent.

Contamination is a preventable primary factor in printed circuit boards. One common source of contamination is flux remaining on the board due to insufficient cleaning. Other contamination can occur during the assembly process, such as fingerprints. CALCE EPSC recommends that statistical process control be used during the manufacturing process to help identify potential contamination sources. The use of conformal coatings is also recommended as a preventative measure to protect against ECM. However, if the conformal coating is applied to a contaminated printed wiring board, ECM may still occur.

Currently, CALCE EPSC is conducting experiments to determine the correlation between chloride concentration and electrochemical migration. CALCE EPSC is continuing ECM experiments in the coming year with the use of fluxes to lay the foundation for developing a time-to-failure model for ECM.

To obtain further information, contact Dr. Michael Osterman at 301-405-8023.
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CALCE Provides Root Cause Analysis for ESD Failures

Electrostatic discharge (ESD) is often a cause for device level failures in electronic equipment but is often left uninvestigated and accepted as inevitable. Semiconductor devices are susceptible to direct, indirect and latent damage when subjected to ESD. Direct damage results from physical destruction or degradation of a part of a device. An indirect failure occurs when a device changes state due to conducted or radiated electromagnetic interference (EMI) initiated by the discharge. Latent failures are time-dependent phenomena. They occur when a discharge makes a device susceptible to failures during operation; although there is no apparent damage. ESD is often a common scapegoat for unexplained failures. Further, there is a misunderstanding regarding the differences between electrical overstress (EOS) and ESD failures, and relationships between them.

For the past three years, the CALCE EPSC has worked with companies including Samsung and Huawei, China to resolve suspected ESD and EOS problems. The center conducted a physics-of-failure based root cause analysis to identify the failure sites and mechanisms. The analysis process starts with observation, recognition, recording, and reporting of the discrepant condition, fact gathering through failure mode and effect analysis, and part analysis, such as preliminary analysis, external package analysis, physical dissection, decapsulation, verification of failure after decapsulation and internal visual inspection.

The CALCE EPSC has developed a team dedicated to ESD related failure analysis to help companies identify whether a failure is caused by EOS, ESD or other mechanisms and suggest best methods to replicate failures; to test parts to the industry accepted standard human body model (HBM), charged body model (CBM) and machine model (MM). The team can also help develop an ESD control program. Benefits include not only reduced ESD failures but also other possible reliability issues that may have been masked by ESD. The team is headed by industry-experienced professionals equipped with state-of-the-art instruments. Contact Dr. Osterman for further information.
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CALCE/University of Missouri Collaboration on Unique Radiation Shielding

The CALCE EPSC and the nuclear reactor facility at the University of Missouri-Rolla teamed up to explore lower cost alternatives to mitigate the negative effects of ionizing radiation on COTS components. Testing of sample parts under different shielding conditions revealed that the polymer shielding process is a promising alternative to radiation hardening. Further work is continuing for different part types and opto-electronic components. Rather than develop radiation-hardened electronics at high cost, the project assessed the potential for shielding of radiation-resistant polymer/tungsten carbide composites relative to a lead (Pb) reference. Malfunctions of components are either due to a cumulative ionizing dose and/or a single event effect, whereby a single, energetic dose or particle disables the part. Contact Dr. Diganta Das or Dr. Akira Tokuhiro for further details.
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CALCE Collaborating with Merix on NSF Premise Program Grant

CALCE EPSC is collaborating with Merix, a printed circuit board manufacturer, on a National Science Foundation grant focused on decision-making for environmentally responsible product development. The perspective of this program is that product development is an information flow governed by those who make both design decisions and development decisions under time and budget constraints, i.e., that product development is treated as a decision production system.

At Merix, the focus will be on the generation of material disclosure statements (MDS) that inventory all the materials present in a finished product. Merix is being required to produce material disclosure statements by many of its customers who are already complying with (or preparing to comply with) various types of worldwide environmental legislation. The information flow within Merix, in its supply chain, and to its customers is being modeled to create a representation that identifies the participants, the decision-making and information-processing activities, and the nature of the information flows.

The model will be used to determine the quality standards for material disclosure statements, to identify mismatches between available data and data needed to complete these statements, and to identify other decision-making processes that use similar environmental information.

The University of Maryland has also opened a dialogue with Motorola to understand how a Merix customer is using MDS data and how Motorola will articulate requirements for material disclosure statements to their suppliers and qualify their suppliers to produce MDSs in the future.

For more information, contact Dr. Peter Sandborn at 301- 405-3167.
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