Articles from CALCE News

 Spring/Summer 2005 issue


CALCE EPSC Offers Design Reviews and Reliability

 Capability Audit Programs for Companies

CALCE EPSC has developed proven methods for product design reviews and company-based reliability capability assessment. In a competitive marketplace, manufacturers cannot afford the expense and time involved in producing and qualifying multiple versions of a product before converging on a reliable design. Likewise, equipment manufacturers and system integrators cannot wait until they get their parts or products to determine if they are reliable. Such iterative development processes are costly and preclude the achievement of rapid design cycles.

CALCE EPSC performs design reviews on electronic product designs and prototypes, drawing on the expertise, virtual qualification capabilities, and characterization facilities at the Center. The design reviews aid customers in understanding the reliability risks in their products before the products are released to the field. CALCE has performed over three hundred such design reviews for leading electronics manufacturers.

The CALCE reliability capability evaluation process was developed to assist customers in assessing themselves, as well as prospective suppliers, for their ability to design and manufacture reliable products before they are delivered for use. It is based on reviewing the reliability practices within an organization and evaluating the effectiveness of these practices in meeting the reliability requirements of customers. The CALCE reliability evaluation process consists of:

  • Completion of a CALCE fact-finding data package by the company’s personnel
  • A site visit by a CALCE evaluation team to cooperatively evaluate the company’s reliability objectives and practices
  • A report incorporating all comments, observations and recommendations, usually available within a few weeks after the evaluation

For information on CALCE reliability capability evaluation or CALCE design reviews, contact Prof. Michael Pecht or Dr. Michael H. Azarian or call 1+ 301-405-5323.
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CALCE Leads Sensor Roadmapping Efforts at NEMI

The development of advanced sensor technologies offers industry many new commercial and technical opportunities. Key features of sensor technologies that drive widespread implementation across all sensor types are low price, small size, robustness, dispensability, the ability to be self-calibrating, and a high level of integration.

To help empower industry to make correct product and technology investment choices, NEMI (the National Electronics Manufacturing Initiative), in collaboration with CALCE EPSC, has developed a sensors technology roadmap. CALCE EPSC has led the Sensors Technology Working Group, which has analyzed technological and manufacturing capabilities and compared these to existing and anticipated sensor applications. The initial roadmap centers primarily on automotive applications for sensors. Future efforts will examine applications across multiple market sectors, including transportation, health care, consumer electronics, industrial and telecommunications infrastructure, defense, and security.

The application of MEMS technologies to sensors has great impact on automotive applications. The shifting emphasis of MEMS processing from bulk to surface micromachining is expected to enable further miniaturization and reduced cost of MEMS sensors, opening new applications. Subsystems in automobiles relying on advanced sensors include engine control, safety systems, vehicle control, collision avoidance, passenger comfort, and vehicle security. Legislation governing tire safety for passenger vehicles is expected to drive future growth in pressure monitoring systems.

Realization of the potential for embedded sensors will require development of miniaturized sensor elements, integrated control systems, and micro-actuators which can all be interconnected in a single package with a small form factor. Advances in microelectronic fabrication technologies, combined with system-on-chip design, will lead to rapid development of the control systems needed for smart embedded sensors. Packaging technology must evolve towards higher levels of integration using system-in-package solutions, sometimes as an intermediate step towards eventual system-on-chip implementation.

A number of important disruptive technologies (nanotechnology, micro-fluidics, distributed sensing, advanced micro-optics) are poised to have a substantial impact on the commercial marketplace for sensors as we enter the next decade. Technology gaps hindering the full realization of market opportunity exist for ultra-small and implantable biosensors and self-contained sensors integrating miniaturized energy-source technologies. The need exists for a wider selection of biocompatible materials for packaging of biosensors, backed by long-term reliability and safety data. Significant non-technical barriers to sensor technology development include inadequate cross-disciplinary collaboration, a shortage of qualified human resources, and a lack of widely established and accepted standardization, especially with respect to communication protocols.

For further information, please contact Dr. Michael H. Azarian or Dr. Sanka Ganesan or call 1+301-405-5323.
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Guideline Development for Assessment of Lead Refinishing by

 Solder Dipping

CALCE is leading the technical analysis task force in the NAVY Transformational Manufacturing Technology Initiative Robotic Solder Dip Project for mitigation of tin whisker risk. Tin-lead or pure tin-plated parts are prone to tin whisker formation, a major reliability concern, especially for long-term and critical applications, such as those in the fields of military or defense. One possible mitigation strategy reflects the expectation that tin-plated IC devices could be refinished by solder dipping to remove the tin plating by traditional eutectic tin-lead plating. Questions remain regarding possible damage induced inside the IC packages due to the thermal shock experienced during solder dipping, and the effects of additional processing steps on the quality of the plating.

This project, funded by the Office of Naval Research, studies the effects of refinishing previously plated IC leads with solder dipping. The key performers include the NAVY BMP Center of Excellence (College Park, MD), Raytheon Missile Systems (Tucson, AZ), Raytheon Integrated Defense Systems (Tewksbury, MA), Corfin Industries (Salem, NH), and CALCE EPSC. The objectives include the following:

  1. Examination of dimensional properties of the lead cross sections, plating and intermetallic layers after solder dipping in comparison to the as-received parts
  2. Determination of whether the process results in deterioration of part reliability
  3. Determination of whether solder dipping has a detrimental effect on the moisture sensitivity level of the parts

These objectives are being addressed by studying the following key areas:

  1. Dimensional changes and geometrical issues for the new finish
  2. Formation of intermetallics
  3. Thermal degradation at package interfaces leading to delamination
  4. Dissolution of the pre-existing plating
  5. Wetting of leads with new solder-dipped finish

Issues related to handling damages and coplanarity are also being investigated.

Twenty-three different electronic parts have been selected for this evaluation, covering various package types, plating materials, lead materials, and lead pitch. The parts go through five major stages during the evaluation process: inspection of as-received parts, initial electrical testing, solder dipping, post-dip electrical testing, and environmental (temperature cycling and temperature humidity) exposure.

CALCE is evaluating parts taken off the flow after each stage for possible damages that may have been caused by the solder-dipping process. Conclusions on the effects of refinishing by solder dipping are made by comparison of these test results across the different process stages. Various destructive and non-destructive tests, along with analysis techniques, are deployed to evaluate the parts at each of these stages. The result of these analyses will be a guideline document on the applicability of the solder-dipping process for various part types.

For more information, contact Dr. Diganta Das at 1+301-405-5770, or Dr. Sanka Ganesan at 1+301-405-0765.
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CALCE Finds that Pb-free Electronics Can Be More Reliable,

 but Not Always

As the electronics industry transitions from conventional tin-lead (SnPb) solder to lead-free solders (e.g., tin-silver-copper (SnAgCu), a great deal of time and effort has been spent on conducting tests to determine the reliability of the new solders. A review of the test results reported in the open literature is encouraging in that the durability of the SnAgCu solder for compliant leaded and area-array technologies appears to be superior to joints formed with SnPb. However, there have been instances where the Pb-free interconnects appear to be less durable (fail sooner) than their SnPb counter-parts. From these conflicting results, it is clear that a transition region exists where SnPb interconnects are likely to outperform Pb-free interconnects, and visa versa. The actual crossover is dependent on the stress-strain history in the solder, which in turn is influenced by temperature and dwell times. As a result of early test failures, concern has arisen that certain Pb-free solders may not be suitable for some use (application) environments.

In order to fully understand the impact of solder change on interconnect durability, CALCE is conducting a designed experiment to examine the influence of cyclic temperature and dwell time on the fatigue life of Pb-free solders (SnAgCu and SnAg), as compared to SnPb. The test specimen for this experiment is a printed wiring assembly with four ceramic chip carriers attached to the printed wiring board. The chip carriers are attached to the printed wiring board with SnPb, SnAgCu, and SnAg solders. Testing is being conducted to 100% failure.

Thus far, the major finding has been that elevated temperatures and extended dwells have a stronger influence on reducing the solder attach life of Pb-free (SnAgCu and SnAg) solders than on SnPb solder. In fact, when the peak temperature was held at 125ºC, raising the cyclic mean temperature resulted in a shorter life for Pb-free solders than for SnPb solder for the components under test.

While the testing has not demonstrated a greatly elevated reliability risk with Pb-free solders, it has clearly demonstrated that the acceleration factor on Pb-free solder joints is substantially different from that on SnPb solder joints. It also raises the question of the adequacy of existing modeling techniques for determining acceleration factors between product qualification tests and field conditions.

The results from these tests are being used to update the rapid life assessment models within calcePWA software and the model constants and strategies used for detailed finite element modeling of unique solder geometries. The update to the calcePWA software will allow simulation-assisted reliability assessment (SARA) for Pb-free electronic hardware. This simulation capability is being used by many organizations to review product designs that are transitioning to Pb-free assemblies. With the knowledge gained from these test results, CALCE Consortium members will have greater confidence in conducting qualification tests and relating those test results to field life requirements.

For more information of the Pb-free efforts being conducted by CALCE and how to participate in these studies, please contact Dr. Michael Osterman at 1+301-405-8023.
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Reliability Assessment of Electronic Assemblies under High-G 

(Artillery Launch) Loads

CALCE has been active in assessing the shock loading reliability of electronic products. CALCE is now working with the Army Research Labs (ARL) and the University of Nevada, Las Vegas, in a multi-year project that will identify the most dominant failure sites and failure mechanisms in high-G, gun-launched smart munitions containing electronic components and assemblies. The project is considering gun-launch conditions ranging from current artillery peak G-level setback loads of 15,000 G through next-generation artillery of 60,000+ peak G-levels. Only one-directional G-loading is being considered. Spin is not being considered, as next-generation smart munitions will typically not be launched through rifled gun tubes.

The first objective of the project is to provide electronic assembly and component selection design guidelines for high-G applications. The final objective is to develop validated design models and methodologies that can be used for the rapid reliability assessment and virtual qualification of electronic assemblies in smart artillery projectiles.

As next-generation electronic components become available and there is need for them to be considered for use in high-G environments, a generic approach is necessary. The practical objective of the current task is to evaluate a subset of current-generation components and develop failure models and virtual qualification tools that apply to these components. This subset of components is being selected based upon usage and ruggedness concerns expressed by designers and UMD/ARL experience. The key deliverable from this task will be a demonstrated methodology and approach to reliability assessment that can also be applied to future electronic components that will be subjected to artillery launch loads.

The task relies upon an integrated experimental and computer simulation-based approach. It brings together the talents of the University of Maryland’s CALCE Center with its physics of failure experience and approach to electronics reliability assessment, ARL and its experience and facilities using air guns to simulate artillery launch loads, and UNLV and ARL with their dynamic FEA modeling experience. In very general terms, an experimental program will be conducted to generate a well-characterized failure database of components and assemblies subjected to high-G loads. Computer simulation will be used to quantify the exact load or stress levels at each identified failure site.

Most researchers investigating high-G level failures in electronics rely upon computer simulation only and hypothesize about potential failures. This is a good starting place, but the hypothesized failure models need experimental confirmation to understand such details as dynamic strength versus static strength. Additional issues such as the dynamic interaction of the mitigator material and the interaction of the various types of potting compounds can only be answered via carefully designed experiments. Due to high costs in time as well as money, a wide enough variety of careful experiments has not previously been conducted to accurately develop failure models for electronics in a high-G environment.

For more information, please contact Prof. Don Barker at 1+301-405-5264.
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Humidity Degradation of Base Metal Electrode Multilayer 

Ceramic Capacitors

As integrated circuit (IC) progress has driven more functionality onto each integrated circuit die, fewer ICs have been required on each printed wiring board. At the same time, the trends toward lower IC voltages and to higher operating frequencies have required more passives to maintain signal integrity. For example, approximately 90% of the electronic components on a cell phone are passive components, of which 60% are capacitors, and most of these capacitors are multilayer ceramic capacitors (MLCC). Capacitance has been improved by reducing the dielectric thickness between electrodes, by increasing the number of electrodes, and by introducing new, smaller capacitor sizes. The smallest capacitor size in volume production is only 0.6 mm by 0.4 mm by 0.2 mm (EIA 01005), approximately the diameter of a human hair.

MLCC electrodes and terminations had been composed of an alloy of palladium and silver in order to make the melting temperature compatible with the sintering temperature of barium titanate. Beginning in the late 1990s, the price of palladium rocketed from $125 to almost $1100 per troy ounce. The capacitor industry responded by making electrodes with nickel, a design referred to as base metal electrodes (BME). Today, most MLCCs are BME parts.

Barium titanate is used in capacitors because it has a high dielectric constant as a result of its atomic structure. Barium titanate at room temperature has a tetragonal (cuboid) shape. The titanium atom in the center position of a barium titanate cuboid is often described as a “rattling titanium” atom, because it can be in one of two positions along the unit cell’s longer direction. Within each crystalline grain of barium titanate there are domains that are separated by nanometer scale transitions called walls. Within each domain, titanium atoms are positioned in one head-to-tail direction. In the adjacent domain, the titanium atoms are positioned in the opposite direction. The ordering might be envisioned as vehicles on strips of highways laid next to another.

Application of a voltage to the MLCC generates an electric field between electrodes that forces individual titanium atoms to switch positions to line up with the field, creating a polarization. Many unit cell polarization vectors combine to generate what we measure as net capacitance.

It was already known that barium titanate capacitors lose capacitance over time due to changes in mechanical stresses in the barium titanate after firing. This “aging” effect involves atomic adjustment of stresses within the crystalline grains and tends to be very gradual. Designers build in capacitance margin over product life to allow for this type of aging. However, when BME capacitors are exposed to moisture, they can exhibit another type of aging.

The new aging was first discovered when both precious metal and BME EIA 0805 capacitors were subjected to autoclave (120ºC/100%RH) testing. It was found that the precious metal capacitors aged according to the well-known aging mechanism (less than 3% from their starting values), but the BME capacitors degraded to below the -30% criterion at 500 hours of exposure. Attempts to restore the capacitance after the autoclave exposure, using a standard industry method called deaging, produced different results for the precious metal and the BME capacitors. The PME capacitors returned to their initial values, but the BME capacitors did not recover. This is because the humidity degradation mechanism is different than the mechanism for the known aging.

The reasons for this new failure mechanism are complex, and two theories were hypothesized. The first was that there could be oxidation or corrosion of the nickel plates. However, ion beam milling and electron microscopy of the electrode-to-dielectric-to-termination interface, electron backscatter diffraction (EBSD) of the polycrystalline grain structure of the capacitors, and dye penetrant found no possible interconnected path for moisture to flow into the capacitor body from the capacitor surface. Capacitors were also monitored for weight gain after various moisture exposures using balances and thermogravimetric analysis (TGA) with argon purge gas. No weight change was detected by either method, and it was finally concluded that moisture could not be entering the capacitor bodies. Finally, BME capacitors were subjected to long-term autoclave and then internally assessed using x-ray photoelectron spectroscopy. It was found that nickel oxide was not in the body of the capacitors. In other words, the decrease in net capacitance was not due to plate oxidation or increased plate spacing from an oxidation process.

The other hypothesis was that the loss of capacitance was due to oxygen vacancies. When a barium titanate unit cell loses an oxygen atom, we call that an oxygen vacancy. If this oxygen vacancy is a random defect, there is no measurable change to the net capacitance. However, if many barium titanate unit cells loose an oxygen atom, then there will be a net reduction in capacitance. The capacitance loss can be significant if multiple cells affected by oxygen atom loss are lined up.

In order for oxygen vacancies to move within the capacitor, they must cross crystalline grain boundaries in the barium titanate. Since the size of the dielectric grains does not change as the industry shrinks capacitor size, and shrinking the size implies thinner barium layers between electrodes, there are fewer grains that ions must cross. With fewer grain boundaries to cross, there is less resistance to ion flow. In addition, as the MLCC size shrinks, the ratio of the surface area – where the barium atoms are being removed – to volume grows, bringing the surface charge and oxygen vacancies into more intimate interaction. In these two ways, reducing the size makes the newer BME capacitors more vulnerable.

Experiments showed that the new aging followed an exponential rule, just as would be expected in a diffusion process. This process can occur in the autoclave testing and perhaps in the field due to long-term humidity exposures. The result is degradation of capacitance. Capacitor degradation due to the new aging is most problematic in high-humidity environments, with high-value capacitors (thinner barium titanate layers). Unfortunately, standard humidity life testing, such as JESD-22 THB, HAST and autoclave, will likely not uncover this problem. Therefore, poor reliability due to degradation of BME MLCC capacitance may catch manufacturers and consumers by surprise.

To obtain more information on humidity degradation of base metal electrode multilayer ceramic capacitors, please contact Prof. Michael Pecht at 1+301-405-5323.
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Prediction of Transient Component-Board Heat Transfer

Electronic parts are subjected to transient thermal environments in the course of their life, induced by assembly processes or dynamic operating conditions. In such conditions, large spatial and temporal temperature gradients can develop in electronic packages and assemblies that can adversely impact device reliability or electrical performance.

Progress in electronics reliability prediction has been hampered by the lack of methods to accurately predict such temperature gradients. Numerical analysis of heat transfer in electronic equipment has generally been confined to steady-state operation. This is essentially attributed to previous reliability prediction methods focusing on steady-state temperature, design for continuous operation, and prohibitive computational requirements for transient analysis. To further ease computational constraints, numerical analysis of transient component heat transfer is generally undertaken using non-conjugate methods. Such analyses are confined to the modeling of conduction, with convective heat transfer represented by a semi-empirical effective heat transfer coefficient prescribed at the solid-fluid interface. This approach is not appropriate for the majority of air-cooled applications, or for convectional reflow soldering processes, in which board heat transfer is highly conjugate.

CALCE EPSC has assessed the need for conjugate (conduction/convection) analysis, both for component temperature and thermomechanical behavior prediction in operational, assembly, and reliability qualification environments. The capability of computational fluid dynamics (CFD) analysis to predict component transient conjugate heat transfer in air temperature and power cycling conditions representative of reliability qualification tests or assembly processes was investigated using an industry-standard CFD code for the thermal analysis of electronics. Based on a range of experimental benchmarks, component transient thermal behavior was found to be accurately predicted for a single board-mounted PQFP. The results suggest that CFD analysis could play an important role in providing critical temperature boundary conditions for component electrical performance and thermomechanical behavior analyses, designing component reliability qualification tests involving power and air temperature cycling, and optimizing convective assembly processes. The need for accurate virtual prototyping of assembly processes is emphasized by the introduction of lead-free technology, which will require extensive requalification of the reflow processes, partly resulting from higher reflow temperatures relative to eutectic lead-tin solder. The transient thermal analysis approach investigated by CALCE could contribute to more accurate damage estimation and life prediction due to specific failure mechanisms influenced by temperature, relative to predictions obtained using non-conjugate heat transfer solution methods.

Future work will investigate the impact of both more complex aerodynamic conditions and component thermal interaction on the prediction of transient heat transfer for forced-air-cooled, multi-component board applications.

For further information, please contact Dr. Peter Rodgers at 1+301-405-8126 or Dr. Valérie Eveloy at 1+301-405-5901.
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CALCE Wins NSF Grant to Work on Forecasting Electronic 

Part Obsolescence

The CALCE Center and the University of Massachusetts, in collaboration with PartMiner Information Services, Inc., have been awarded an NSF grant to explore how existing academic and industrial resources can be combined to significantly impact proactive obsolescence forecasting and management.

CALCE will work on a data-mining-based approach to electronic part obsolescence forecasting. Part obsolescence dates (the date on which the part is no longer procurable from its original source) are important inputs during design planning. Most electronic part obsolescence forecasting algorithms are based (at least in part) on the development of models for the part’s life cycle. Traditional methods of life-cycle forecasting utilized in commercially available tools and services are ordinal-scale-based approaches, in which the life cycle stage of the part is determined from an array of technological and market attributes. Existing commercial forecasting tools are good at articulating the current state of a part’s availability and identifying alternatives, but are limited in their capability to forecast future obsolescence dates and cannot provide quantitative confidence limits when predicting future obsolescence. More accurate forecasts, or at least forecasts with a quantifiable accuracy, open the door to the use of life-cycle planning tools (like that CALCE Mitigation of Obsolescence Cost Analysis - MOCA tool) that could lead to more significant sustainment cost avoidance.

In this NSF grant, CALCE will demonstrate the use of data-mining-based algorithms to augment commercial obsolescence risk databases, increasing their predictive capabilities substantially. Several years ago, the University of Maryland developed an obsolescence forecasting methodology based on forecasting part sales curves. In this method, sales data for an electronic part is curve fit. The attributes of the curve fits (e.g., mean and standard deviation for sales data fitted with a Gaussian) are plotted, and trend equations are created that can be used for predicting the life-cycle curve of future versions of the part type, (Solomon et al., IEEE Trans on CPMT, Dec. 2000). The original obsolescence forecasting approach used a fixed window of obsolescence determined as a fixed number of standard deviations from the peak sales year of the part. An extension of this methodology that increases the accuracy of the forecasts is the calculation of electronic part vendor-specific windows of obsolescence using historical last-order or last-ship dates. The extended methodology will not only enable more accurate obsolescence forecasts but will also generate forecasts for user-specified confidence levels. The methodology will be demonstrated on both individual parts and modules.

Initially the data mining methodology has been applied to part types with well defined primary attributes, e.g., flash memory. The methodology has also been demonstrated on composite structures such as memory modules. Preliminary results from this work will be presented at the DMSMS Conference in Nashville, TN in April. Extensions of the data mining approach to part types with either multiple driving attributes or indeterminate driving attributes is the focus of the work to be performed in this project during 2005.

For further information on this work, contact Prof. Peter Sandborn at 1+301-405-3167.
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Samsung Techwin Engineers and Prof. B. T. Han Won 

Gold Award for Best Paper

Samsung Techwin Engineers and Prof. B. T. Han won the Gold Award for the best paper in the Analysis and Simulation Session at the 1st Samsung Technical Conference held on November 9–12, 2004. The title of the paper was “Predictive Modeling Solutions for Next Generation LCD Driver IC Chip Package.” For more information please contact Prof. B.T. Han at 1+301-405-5255.
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CALCE Offering Course at SEMI-THERM

Dr. Diganta Das and Dr. Peter Rodgers have been invited to give a one-day professional development course entitled “How to Select and Use Electronic Parts Outside the Manufacturer-Specified Temperature Range” at the 21st SEMI-THERM symposium, to be held in San Jose, CA, March 13, 2005. This course presents specific methodologies for uprating of electronic parts. The course is meant to support the complete supply chain that may provide or use uprated parts, including product manufacturers, electrical test laboratories, aftermarket part suppliers, regulatory bodies, and part manufacturers. Further information and registration details for this course are given at http://www.semi-therm.org.
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Dr. Valérie Eveloy Joins CALCE EPSC

Dr. Valérie Eveloy has joined CALCE EPSC as a Research Scientist. She holds a Ph.D. degree in mechanical engineering from Dublin City University, Ireland, and a M.Sc. degree in physical engineering from the National Institute of Applied Science (INSA), France. She has been involved in the thermal management, packaging, and reliability of electronic equipment for ten years, and was previously with Nokia, Finland, and Electronics Thermal Management Ltd., Ireland. Her current activities at CALCE EPSC are focused on human health monitoring. Other research interests include electronics thermal management and computational fluid dynamics. She has authored or co-authored over thirty-five journal and conference publications. Dr. Eveloy is a member of several international conference program committees focused on thermal phenomena in electronic systems.
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New Thermal Characterization Equipment Acquired by 

CALCE EPSC

CALCE EPSC has recently acquired a TC ProbeTM thermal conductivity instrument from Mathias Instruments. This equipment is designed to measure the thermo-physical properties of solids, liquids and greases using a non-destructive technique. This instrument also enables depth-profiling and changes in thermal properties to be assessed over time as the result of physical and/or chemical processes occurring within the sample. This equipment will extend CALCE’s thermal interface material (TIM) research capabilities. CALCE EPSC currently has a laser flash unit that permits the measurement of bulk and interfacial thermal contact resistance of interface materials, such as adhesive-based materials (e.g., epoxies and pressure sensitive adhesive tapes) and solders. For further information, contact Dr. Peter Rodgers at 1+301-405-8126.
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